SiO2添加剂对防热透波一体化复相陶瓷结构及性能的影响

The influence of SiO2 additive on the structure and properties of heat-proof and wave-transparent composite ceramics

  • 摘要: 为研究能满足高马赫数飞行条件下的防热、承载、透波等要求的防热透波一体化材料,文章采用SiO2作为添加剂,添加到多孔Si3N4复相陶瓷中,通过调控SiO2的含量(质量占比),研究添加后材料的气孔率、孔径分布、物相组成、显微结构、力学性能及透波性能。结果表明,多孔Si3N4复相陶瓷的气孔率随着SiO2含量的提高而降低,抗弯强度随着SiO2的含量提高而上升,透波性能随着SiO2含量的提高先上升后略微下降,说明SiO2的添加,既促进了Si3N4的烧结,又在一定程度上提高了其介电性能。添加7.5 wt%的SiO2到多孔BN/Si3N4复相陶瓷中可以获得较理想的防热透波综合性能。

     

    Abstract: In the heat-proof and wave-transparent materials for the antenna housing used under high Ma conditions, SiO2 is added to the porous Si3N4 composite ceramic as the additive. The porosity, the pore size distribution, the phase composition, the microstructure, the mechanical properties, and the wave permeability of porous Si3N4 composite ceramic are studied by adjusting the content of SiO2. It is shown that with the increase of the content of SiO2, the porosity of the porous Si3N4 composites decreases, the bending strength increases, and the wave permeability first increases and then decreases. The introduction of SiO2 not only promotes the sintering process but also improves the mechanical and dielectric properties of the porous Si3N4 composite ceramic. With Si3N4 being combined with 7.5 wt% SiO2, better desirable mechanical and dielectric performance is achieved.

     

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